Give me
the simplest form of matter and motion,
and I will build, out
of them, the world of
Nature.
"Give
me matter, and I will construct a
world out of it."
Immanuel
Kant, Kant's Cosmology
("Universal
Natural History and Theory Of
Heavens")
13. Chemical
Element Classification (Chemclass)
In the previous
page, we began classifying the
chemical elements (chemels) trough their
various properties. The most
general chemel classification
(chemclass) is that a chemel can be either stable
or unstable.
A
stable chemel (stachem) can
further be classified as being
either active or inactive. Due to the preservation
tendency mark of creation (PT-UMOC), to preserve
their stability, stachems must be endowed,
from their birth, with a locking
mechanism that could be called a chemical
lock (chemlock).
The "active" stable
chemels are
characterized by being
open to combine, when
in contact with other
chemels, into various
aggregates or
formations, called chemical
composites
(chemcomps),
that appear to exert
an aura of saturation
and completeness
(sac).
.The "inactive" stable
chemels, on the other
hand, seem to be
locked in a dormant,
non-reactive state,
when in contact with
other chemels,
appearing of
displaying an aura of
being already saturated
and complete (sac).
.That saturation
and completeness
(sac)characteristic,
that appears to exist
and be central to all
chemelscaught
our attention in a
most profound way,
leading us to
recognize
The
Seventeen Foundational
Universal
Recognition Of
Nature
(17thFURON): The
Universal
Principle Of
Saturation (TUPOS)
All matter has the natural tendency to become and
stay saturated.
The saturated
matter (satma)
is a "closed-in"
substance that is
inactive and
"complete" while
the unsaturated
matter, called active
matter (actma),is
a substance that
is active and
"incomplete",
being open to
combine with other
chemels
to form new stable
"saturated" combined
entities. (If those
combined entities
are made of the same
chemels,
they are called molecules; if
not, they are called
compounds.)
Thus, for instance, through the combination of two (2)
Oxygen-chemels,
we get the
Oxygen (O2)
moleculewhile
through the
combination of
two (2)
Hydrogen-chemels
with one (1)
Oxygen-chemel,
we get the
Water (H2O)
compound.
!
Remark:
It
is important
to recognize
that TUPOS
exists because
of Downlev --the ultimate physical law of Nature (Uplon)
detailed as
follows:
• i)Actma
is fueled by
the ergolevelingprocess
dictated by Downlevand
• ii)Satmais
protected by Downlev
through its objective of existence of not allowing any permanent deviation from
its stable
state of
existence.
That
protective
reach of Downlev is
an outreach of
the preservation tendency mark of creation (PT-UMOC).
Definitions:
A saturated chemel(chemSAT) is a chemel that exists in a closed,
unresponsive
state, that
stays
unaffected by
being in
contact with
any other
chemels,
reflecting as
such, an aura
of saturation
and
completeness (sac).
(By "saturated", in this context, is meant of a
chemel not
accepting any
more
electrons.)
Remark: There is no guaranty, of course, that a chemel
in contact
with a chemSAT
is not being
able to
"steal"
electrons from
it, to form in
the end, a compound with it. For that to happen, the “pirate” chemel
(pirac) must
somehow be
able to break
the chemSAT's
chemlock.
An active chemel(chemACT) is a chemel that exists in an open
state, ready
to react and
interlock with
some other
contacting
chemels, to
form a
"saturated"chemcomp.
Thus, we can talk about the two kinds of stachemsthat exist in Nature:
the unresponsive
ChemSATsand, the
responsiveChemACTs.
Both those
types of stachems
exist because
of Downlev.
With that stachemclassification
behind us, we now continue by
examining their presence, if any,
in the Periodic Table of
Chemels (PETAC).
Are
There Any ChemSAT in the
Periodic Table of Chemels
(PETAC)?
From various
experimental data, it was
gradually recognized that the Helium group, called the
noble gases (nobgas) group,
appeared to be the only group that
did not react or combine when it
was placed in contact with other chemels. Because of that
non-reactivity towards other chemels when in contact,
it was reasoned that the nobgas group was
comprised of chemels that were
somehow "full," "complete," or
"saturated." WHAT then, those chemels of
the nobgas group had in
common, that set them apart, and
made them unreactive or
unresponsive towards other chemels
in contact? Upon the
introduction of Niels Bohr's
planetary structural model of the
atom (now, abolished), it was
reasoned that the outer
"planetary" electrons, and only
them, were the ones involved in a
chemical reaction (chemrec). As such, it was further
reasoned that the outer ring
(oring) of electrons must
hold the key as to WHY the chemels of the nobgas group stay
neutral towards other chemels in contact. Thus,
it was conjectured that if the oring is packed to its
fullest capacity, i.e., being saturated,
then those saturated orings
(sators) hold the ticket to
their neutrality.
With that
understanding, that all orings of nobgases are saturated (being, as such,
sators), the next
logical question, that would have
required an answer for the study
of the sators
of
nobgases, would have been
perhaps this one, regarding their
sizes: WERE those satorsof the
same size for each chemel of nobgases, or do they
differ for each member of the nobgas group, and thus
differ in their packing capacity? That question
which was never asked, much less
answered, can be answered in here
through:
The Packing
Corollary Of Sators
(PACOS)
The
packing capacity of
a sator is
not function of its
size.
Proof:
This
is a direct result
springing from TELSAT.
Regardless of their
sizes, all sators from
the nobgas group
will contain the same
maximum finite
(Maxfin) number
of packed electrons.
QED.
WHAT then that maximum finite
(Maxfin) number of packed
electrons is for a sator of the nobgas group?
Well, the answer
to that, most certainly, could not
come from the blueprint of TRUTON
presented herein. And that is
because that question is not
answerable here no more than
answering WHY the number 82(and no
other number) is the Maxfin number of protons
that a NUC must have in
order for its chemel to say
nonradioactive.
The natural
radioactivity (narad) begins indeed
with the chemel 83 in PETAC that is the Bismuth (83Bi). In short, Maxfin 82 corresponding to
Lead (82Pb), is not a result
emerging from TRUTON, but is one
resulted from the experimental
data (experda).
As such, that sought Maxfinanswer for the nobgas group must come
from some other place,
specifically from conjectures
derived from the study of chemical
reactions (chemrecs).
Richard Abegg
In 1904, Richard Abegg,
experimenting with the combining
properties of Sulfur (16S),
noticed that when combined with
the Hydrogen (1H)
in obtaining the Hydrogen Sulfite (H2S)
--Sulfur exhibited a lost
of two (-2)
electrons, but when combined with
Oxygen (8O)
and the Hydrogen (1H)
in obtaining Sulfuric Acid (H2SO4)
-- Sulfur gained six (+6)
electrons: two (+2) from the
Hydrogen and
four (+4) from the Oxygen. As such, the
combined absolute range of
the Sulfur from the
minus 2 to the plus 6 of the two
performed chemrecs amounted to the
range sum of eight (8).
Gilbert N.
Lewis
Irving
Langmuir
Stunningly from
there, Abegg extrapolated that
finding with the Sulfur, for all chemels! The empirical
embryonal "Octet Rule" was
born now in several stages.
First, with that
extrapolation, the so-called "Rule
of Eight" was born. Then, in
1916, that empirical rule was
picked up by Gilbert N. Lewis
in his seminal cubic atom theory
calling it, for the first time,
the "Abegg's Rule." From
there, in 1919, Irving
Langmuir, developed his own
empirical "octet theory"
that eventually become cemented as
the "Octet Rule."
Through the "Octet Rule" conjecture, the nobgas group was now
understood to have in their orings that saturated value of eight (8) electrons that
represented the Maxfin number.
The number of
electrons that a ChemACT needs to have for
reaching the Octet Ruleformation for its
oring or ovalonis called its valence.
Thus, the valence number
(valnu) is a whole number
without a sign and, as such, from
valnu, we cannot have
any indication whether the ChemACT has
gained (+) or lost (-)
electrons in its oring (ovalon)during its
interaction with other chemel. The
range of valnu is, as such, from
1 to 7, since 8 is a complete
octet.
That limitation
with the valnu representation
has been eliminated with the
introduction of the oxidation
number (oxinum) that is a
number that keeps track of the
electrons in the oring (ovalon) of the chemel
and incorporates, as such, both
signs:
with
the negative (-) sign
when there is a gain
of the (negative)
electrons and, with the positive
(+) sign when there is
a lost.
Remarks:
(1-7) . . . (±)
1. In the modern
language of Chemistry, the Abegg's Rule can be expressed
through the concept of valence and expanded into
the oxidationstate concept
that, as noted, differentiate an
atom that is an electron grabber
that gains electrons (negative
valence) from the one, that is an
electron loser by losing electrons
(positive valence). 2. In the TRUTON
lingo, we note that the oring is the ovalon and, that the saturated oring
(sator) is the saturated
ovalon (satov).
The
Octet Rule conjecture has
been paramount for providing the
general blueprint of how ChemACTs will react
towards other like chemels: that
of getting a saturated 8-electron
pack into their outer ring --the oring (i.e., into their
ovalon), i.e., that of
getting a satovmodulo the
Octet Rule.
The combining
capacity of a ChemSAT is therefore (as
recognized through the blueprint
paved by the Octet Rule) a function of
the numbers of the outer
electrons, called valence
electrons (valELs), that
were needed for its ovalon to became
saturated i.e., to become a satov. That combining
capacity led, as noted, to the
concept of valence that was created
to show how a chemical bond
(chembond) is being formed.
That ChemACTs can unite in
creating a chembondthrough their
outer valELs of their
respective ovalons, led to the
recognition that their unification
can be achieved through two, and
only two, distinct pathways:
either
through a sharing or
trough a capture of
the outer valELs,
creating, as such,
either
a covalent bond(coB) or
a ionicbond
(ioB),
respectively
Polar Covalent
(poco) Bonds
By the concomitant
influences supplied by
two uniting ChemACTson
their commonly shared
valence
electrons (valELs),
energy (as in a pull)
is going to be
released that will be
used in cementing the
stability of the chembond.
However,
differentChemACTs will
attract the shared
valence electrons (valELs) with
different
forces. As such, there
is an inequality in
the amount of the
"pull" exerted on its
valence electrons valELs by
the various chemels.
Those
(valELs), as
such, will experience
pulls of various
degree of intensity.
Thus, to each
participating chemel, we
can associate a
measurement for its
tendency to grab or to
pull those valELs.
If
we call electronegativity
(ELneg), the
measurement of a chemel's
strength of that
tendency to grab or to
pull a valence
electron (valELs),
then (as recognized
and developed in the valence
bond theory by
Linus Pauling)
due to that pull
inequality, we can
talk about chemels of highELneg (such
as Fluoride, Oxigen,
Nitrogen, or Chlorine)
or of lowELneg (such
as the alkali metals
or the alkaline earth
metals).
All
this recognition of
different levels of ELneg leads
to the unequal sharing
of valence electrons (valELs)
between chemels, as valELs will
be drawn closer to chemels of
higher ELneg.
A
large difference in ELneg of
its partnering bonding
chemels,
leads to a stronger polar
(ionic)
character of the bond.
The higher the value of the ELneg
of a chemel
is, the more
strongly that
chemel
attracts the
shared valence
electrons (valELs).
As such, chemels with the highest ELnegwill be the prime candidates and suspects to become "pirate" chemelc (piracs) when
facing the nobgas group.
In fact, in 1933, Linus Pauling predicted such a scenario with Fluoride and Oxygen as being the front-runners.
Those
predictions,
such as with
Krypton
Hexaflouride
(KrF6)
or with Xenon
Hexaflouride
(XeF6)
were proved to
be accurate,
indeed.
And 1962,
Neil
Bartlett,
was the first
to report of
the highly
oxidizing
compound
Platinum
Hexafluoride
(PtF6).
He also
reported, in
the same year,
of obtaining
the
synthesized
Xenon
Tetrafluoride
(XeF4)
by exposing a
mixture of
Xenon (Xe)
with Fluorine
(F) to a high
temperature.
After that,
the gate was
quite open in
discovering a
plethora of
additional nobgases compounds. The nobgas group has lost, as such, its "inert" title,
irreversibly.
And speaking of gate
opening, we may want
to note this:
Soon
after the introduction
of the empirical Octet
Rulecemented
in 1919 by IrvingLangmuir, it
was recognized that
with that rule, it
cannot be explained
other chemrecs with
other chemels from
PETAC. As
such, two years later,
in 1921, Langmuir
introduced another
empirical rule --the 18-electron
rule that was
able to explain
partially chemrecs
involving the stable
transition of metal
complexes. Once that
gate with the
empirical rules was
wide open, a flood of
empirical rules
followed with no end
in sight.
With that, Chemistry
has entered now into
its murky zone. The Murky
Zone of Chemistry
(Muzoc) was
born...
Linus
Pauling
With that succinct and incomplete
presentation of the covalent bonds
(coBs), we now tend to
move towards the other type of chembonds:
one, at the ionic
bonds type
On Ionic
Bonds(ioBs)
Ionic bonds
(IoBs) were defined as
chemical bonds (chembonds) where their valence
electrons (valELs) are being
transferred (as opposed to being
shared). However, during those
transfers, the electrons
inevitably will be subject to the
influence of the two atoms that
are being engaged with and, as
such, those transferred electrons
would encounter a certain degree
of a covalent
bond (coB), as well. Thus,
"pure" ioBs do not really
exist in Nature as some sharing,
and thus some degree of covalent bond
(coB),
will always exist.
Because of that
blurring overlap of the two types
of bonds, we can talk about the covalent and the ioniccharacter of
the bond. For a bondto be ionic(ioB), the ionic character must be the
dominant one and reflected in the
difference of electronegativity
(ELneg) that exist
between the two participating chemels. That is to say,
that a ionic
bond (ioB) must be more polar (ionic) than in a covalent
bonding (coB) where electrons
are being shared more equally.
and the other, at the metal
bonds type
On
Metallic Bonding(Meb)
Looking at the Periodic Table
(PETAC) of the chemical
elements (chemels), we note that
the majority of them are metals.
There, in the metal world, each
chemel releases one or more of its
electrons creating collectively a
common "cloud" arena of electrons
that resides between them. That
common ground "cloud" arena is
made from the individual
mini-clouds "parcels" that each
electron is bringing with it
through its carrying XB-cloud.
Due to the lost of
those electrons, those
metal-chemels become now
positively charged. The generated
"cloud" arena of "liberated"
electrons are now being attracted
by a multitude of chemels without
being part of any of them. A
collective common bonding (of the
participating chemels) is being
formed that is the called metallic
bonding (meb). The common
cloud of electrons, characteristic
in a metallic bonding, is
responsible indeed for their good
electrical and thermal properties.
Much, much more, needs to be added
in here for the stable chemels (staches), but now we move on
to the other major type of chemical
elements (chemels) --the unstable
ones.
The unstable
chemels are the radioactive
chemels (radchems) whose Maxfin number is greater
than 82 as noted above.
This subject of the radioactivity has been presented,
in brief, in the page 10, and
it will not be expanded in here.
With this, we are leaving not only
this page, but are leaving this
entire section. Before moving to the
last section of TRUTON, the Evolutionary Biology
section,
we present next a brief outlook of
TRUTON: Present and Future.
.